| 具有双官能团的吡咯环骨架手性配体的合成 |
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| 引用本文： | 李高伟,刘春梅,孟俊,孟青霞,赵文献.具有双官能团的吡咯环骨架手性配体的合成[J].商丘师范学院学报,2012(6):56-58. |
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| 作者姓名： | 李高伟 刘春梅 孟俊 孟青霞 赵文献 |
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| 作者单位： | 商丘师范学院化学化工学院有机新材料合成重点实验室 |
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| 基金项目： | 国家自然科学基金资助项目(20972091);河南省教育厅自然科学研究计划资助项目(2011B150029) |
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| 摘 要： | 以便宜易得α-呋喃甲醛为原料,经Cannizzaro歧化反应制得α-呋喃甲酸,氯化亚砜氯代生成α-呋喃甲酰氯,然后再与L-脯氨醇反应,最终得到新的具有双官能团的吡咯环骨架手性配体,该手性配体的结构经IR,1H NMR和GC-MS等物理手段进行了确证.
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| 关 键 词： | 吡咯环骨架 双官能团 不对称合成 手性配体 |
Synthesis of the pyrrole-based chiral ligand with bifuctional group |
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| LI Gaowei,LIU Chunmei,MENG Jun,MENG Qingxia,ZHAO Wenxian.Synthesis of the pyrrole-based chiral ligand with bifuctional group[J].Journal of Shangqiu Teachers College,2012(6):56-58. |
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| Authors: | LI Gaowei LIU Chunmei MENG Jun MENG Qingxia ZHAO Wenxian |
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| Institution: | (Key Laboratory of New Organic Materials Synthesis,School of Chemistry and Chemical Engineering, Shangqiu Normal University,Shangqiu 476000,China) |
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| Abstract: | Starting from readily available α-furaldehyde,α-furoic acid was prepared by Cannizzaro disproportionation reaction,and α-furoyl chloride was achieved by halogenation with thionyl chloride,the new pyrrole-based chiral ligand containing amido-and ester group was ultimately obtained with L-Prolinol.The structure of the new ligand was confirmed by IR,1H NMR and GC-MS. |
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| Keywords: | pyrrole-based bifunctional group asymmetric synthesis chiral ligand |
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