| 表面活性剂对水溶性氮杂环卡宾钯催化Suzuki反应的影响 |
| |
| 引用本文： | 柳云玲,于宏伟,贾莉,施继成.表面活性剂对水溶性氮杂环卡宾钯催化Suzuki反应的影响[J].宁德师专学报(自然科学版),2012,24(2):113-117. |
| |
| 作者姓名： | 柳云玲 于宏伟 贾莉 施继成 |
| |
| 作者单位： | 1. 福建师范大学化学与化工学院福建省高分子材料重点实验室,福建福州,350007
2. 石家庄学院化工学院,河北石家庄,050035 |
| |
| 摘 要： | 开展了添加表面活性剂对带15个左右的乙二醇单元的氮杂环卡宾钯催化剂（5）在水介质中催化Suzuki偶联反应性能的影响研究;发现常见的阳离子或阴离子表面活性剂均可将催化剂5在水介质中的催化性能恢复到在二氧六环中的水平;故发现了一条提高催化剂5在水介质的性能途径.
|
| 关 键 词： | 水溶性 表面活性剂 水相催化 Pd催化剂 Suzuki反应 |
Influence of surfactant for the water-soluble N-heterocyclic carbene palladium catalyzed Suzuki reaction in water |
| |
| LIU Yun-ling,YU Hong-wei,JIA Li,SHI Ji-cheng.Influence of surfactant for the water-soluble N-heterocyclic carbene palladium catalyzed Suzuki reaction in water[J].Journal of Ningde Teachers College(Natural Science),2012,24(2):113-117. |
| |
| Authors: | LIU Yun-ling YU Hong-wei JIA Li SHI Ji-cheng |
| |
| Institution: | 1.College of Chemistry and Chemical Engineering,Key Laboratory of Polymer Materials of Fujian Province,Fujian Normal University,Fuzhou,Fujian 350007,China; 2.School of Chemical Engineering,Shijiazhuang University,Shijiazhuang,Hebei 050035,China) |
| |
| Abstract: | The influence of surfactant for the N-heterocyclic carbene palladium catalyst（5） with 15 of glycol units has been evaluated.It was found that those routine surfactants can recover the activity of the catalyst 5 for Suzuki reaction carried out in water to the level in 1,4-dioxane,affording another way to improve the activity of 5 in water. |
| |
| Keywords: | water-soluble surfactant aqueous catalysis Pd catalyst Suzuki reaction |
| 本文献已被 维普 万方数据 等数据库收录！ |
