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《江西图书馆学刊》2014,(2):F0003-F0003
采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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《江西图书馆学刊》2014,(6)
采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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《江西图书馆学刊》2014,(4):97-101
采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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浅谈高校图书馆新媒体阅读推广策略 总被引：1，自引：0，他引：1
采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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采用光沉积-液相化学法调节电子流向,构建了直接Z型TiO2/Ag/Ag3PO(4 )(TAAPO)光催化材料.通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱仪以及光致发光(PL)光谱仪等手段对其进行表征,并对其在可见光照射下催化降解环丙沙星(CIP)的性能进行了研究.结果表明,当水体pH为3.0,催化剂分散浓度为0.3 g/L,CIP的初始浓度为15 mg/L时,光催化降解体系能够取得最佳的去除效果.在该组条件下,光照120 min CIP的降解率约为99%,并且在经历4个循环后仍然保持了良好的降解效果.在光催化降解CIP的过程中,主要反应活性物种为超氧自由基(·O2 相似文献
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《文物保护研究》2013,58(4):173-194
AbstractIn the course of a program to develop adhesives for the consolidation of paintings it was found necessary to: (1) define the aims of the research, (2) design tests which would provide information on the mechanical performance (effectiveness) of the adhesives, (3) design tests which would help eliminate adhesives with qualities hazardous to paintings. This paper describes only the tests on the mechanical performance of various adhesives: (1) adhesion to paint films, (2) adhesion to conventional and newly developed lining supports, (3) cold flow of lining adhesives, and (4) rigidity of lining laminates. Formulations of the newly developed adhesives are given. 相似文献
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Marine Cotte Emilie Checroun Wout De Nolf Yoko Taniguchi Laurence De Viguerie Manfred Burghammer 《文物保护研究》2017,62(1):2-23
The origin(s) and role(s) of metal soaps in paints are a worldwide concern today. These hybrid compounds, containing both fatty acid chains and metals associated with a carboxylate function, are increasingly identified in paints. As reviewed in the first part of this work, the presence of metal soaps in paints is differently interpreted in scientific publications: metal soaps are sometimes considered to play a positive role as anchor points, during paint drying processes; they can also be considered as responsible for many degradation processes (protrusions, efflorescences, darkening, etc.). Their origins are also interpreted in various ways. In some paintings (in particular from the twentieth century), they have sometimes introduced on purpose, as additives, to modify the physical properties of the painting materials. In older paintings, metal soaps are usually thought to result from an uncontrolled reaction of oil with lead-based pigments, in particular lead white, red lead, and lead tin yellow. In the second part of this work, the review of historical recipes of lead-based paint shows an important number of recipes based on controlled mixing of oil with lead driers. In the third part, the experimental reproduction of such traditional recipes using walnut oil and litharge (PbO) shows that lead soaps can be formed, both in about one hour at ～100°C, or in about one month at room temperature. It shows as well that after a few years, litharge is no longer detected in the paint medium, while different lead carbonates are. Finally, the micro-infrared spectroscopy and micro-X-ray diffraction re-analysis of protrusions from a nine-year model painting shows together with lead soaps, the presence of Pb5(CO3)3(OH)2O (‘synthetic plumbonacrite’), an unusual phase recently observed in a protrusion from a painting by Vincent Van Gogh. This work highlights (i) the multiple origins and roles of metal soaps in paints and (ii) the importance of combining the analysis of fragments from historical paintings with the analysis and reproduction of historical recipes. In particular, we show that the components detected today in historical paintings may severely differ from those originally used or prepared by the painter, complicating the assessment of the painter's intentions. More than the presence of metal soaps, the key questions to be tackled should be about their origins and (re)mobilization. 相似文献
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金属材料经过热处理过程使材料具有优良的组织和性能,广泛应用于先进科技和日常生活中。金属材料的微观显微组织是研究金属材料组织性能的有效方法。金属材料微观组织的形成是金属材料合金成分在金属晶体晶胞中的溶入析出,金属晶体的晶格结构从体心立方晶格转变成面心立方晶格和密排六方晶格。金属材料不同的热处理过冷转变温度形成不同的微观形态的相结构。金属材料从加热状态冷却到室温,金属材料微观晶格结构的变化我们称之为相变。 相似文献
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Rusciano Frank Louis; Fiske-Rusciano Roberta 《Int. Journal of Public Opinion Research》1990,2(4):305-322
This paper presents a content analysis of the manner in which‘world opinion’ is used in stories and editorialsof two nations' major newspapers. The authors studied the InternationalHerald Tribune and the Frankfurter Allgemeine Zeitung for themonths of February, March, and April 1986 for articles whichcontained implicit or explicit references to ‘world opinion’.These refernces were studied using a pre-designed survey instrument,which analyzed several features of the term's usage. Topicsfor discussion included: (1) the various syonyms for world opinion;(2) the agenda for world opinion; (3) the timing of referenceto particular issues on the agenda; (4) the moral and pragmaticcomponents of world opinion; and (5) the link between worldopinion and the ‘international isolation’ of nationsor individuals. The paper concludes by combining the resultsof the study into a preliminary definition of ‘world opinion’,based upon the common usage of this term. The definition comparesthe characteristics of ‘world opinion’ and ‘publicopinion’, and discusses the possible ramifications ofunderstanding the concept in this manner. 相似文献
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《文物保护研究》2013,58(1):38-41
AbstractA white deposit was observed on the glass lids of boxes used to store archaeological textile fragments for some 40 years. It was identified as sodium formate formed from formaldehyde given off by cardboard in the boxes. Heavy metal ions in some samples of the deposit originated, via the textile fragments, from corroded bronze ornaments in the graves. 相似文献
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《文物保护研究》2013,58(4):215-223
AbstractTwo iron swords from Luristan were examined by X-rays and using metallographic sections. The first sword was shown to have a hilt made of five pieces of metal joined by four rivets, while the pommel was secured by a dowel on the end of the tang. Hilt and blade were sectioned for metallographic study. This showed that while the core of each part was pearlite, decarburization had taken place at the surfaces to give ferritic structures. The second sword was shown to have been made of seven pieces. The pommel was secured as in the first sword, but all other pieces were joined by fitting into prepared slots, the edges of which were burred. A section was cut from the hilt at a point where a decorative band had been applied. This showed large-grained ferrite at the surface and fine-grained ferrite with cementite at the boundaries in the core. It is argued that work previously carried out by other metallographers was inconsistent due to inadequate sampling, and that swords of this type were essentially of wrought iron, the presence of pearlite being accidental rather than intentional. 相似文献
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《文物保护研究》2013,58(4):327-369
AbstractThe restoration of the Hedin altar in Rothenburg o.d.T., dated 1466, is described. The polychromed sculptures were cleaned and loose paint was fixed. Methods and materials used in the restoration of the paintings, the areas polychromed in various techniques and the brocade reliefs are mentioned. The altar was protected from direct sunlight. The construction of the shrine and the technique of carving are extensively discussed. Sculptures made from one piece of lime wood were hollowed out and closed with a plank. Traces of rough finishing are visible. Shrine and predella were polychromed after a preliminary assembly of the sculptures. The various techniques used in the undisfigured polychromy are described as they are observed with the unaided eye. It can be shown that the working methods were rational. The fabrication of relief brocades and the various patterns used are discussed in detail. The treatment of the various paintings on the wings, the predella and the reverse of the shrine is reported. The question is raised to what extent the painter Herlin can also have been responsible for the polychromy. 相似文献
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AbstractThe use of sodium nitrite (NaNO2) as a corrosion inhibitor for wet archeological metal objects presents potential advantages of near neutral pH, low concentration, effectiveness on several metals, and compatibility with organic materials. The effectiveness of NaNO2 as a corrosion inhibitor for storage of chloride-containing marine archeological metal objects from the wreck of the USS Monitor was evaluated using marine-corroded carbon steel analogs. The samples were tested in varying concentrations of NaNO2 and evaluated visually and by monitoring solution chemistry using ion chromatography (IC). It was found that a concentration of 1000 ppm NaNO2, replaced four times, was effective at protecting corroded carbon steel in the presence of chlorides. Nitrite solutions were no more rapid than sodium hydroxide (NaOH) at extracting chlorides from marine steel at equal concentrations and were considerably slower than 2% NaOH. IC analyses indicated that NO2 does not easily oxidize to NO3 under normal conditions, but does so readily when a polarizing current is applied, making nitrites unsuitable for electrolytic reduction treatments. Sodium nitrite does show promise as a storage solution prior to desalination of marine metals or after desalination to prevent flash corrosion during rinsing baths. 相似文献
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A sodium copper formate, first described in 2002, can also form on copper alloys with sodium originating from soda glass hydrolysis. The frequent occurrence (50% of 250 cases of glass-induced metal corrosion) is due to the presence of formaldehyde emissions in storage and its direct reaction to formate in the alkaline surface films. The compound can be produced without the presence of acetate when chalconatronite or metal coupons immersed in soda solution are exposed to formaldehyde vapours. The crystal structure, derived from X-ray powder diffraction, yielded the sum formula Cu4Na4O(HCOO)8(OH)2·4H2O. Except for the absence of acetate in the structure, this is in good agreement with the 2002 publication. To assess which kind of combined glass/metal objects are affected, a number of large museum collections were surveyed. Sodium copper formate was detected as a corrosion product using mainly micro-Raman spectroscopy, for instance, on 18 painted Limoges enamels, eight glass vessels with metal mountings, glass beads on metal wire from 11 bridal crowns, nine Christmas tree balls with wire decoration, 40 pieces of jewellery with glass gems, three daguerreotypes, and one miniature with cover glasses. 相似文献