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1.
Light-induced color changes and chemical modification of treated and untreated chestnut wood surface
AbstractThe aim of this work is to study the surface modifications of chestnut (Castanea sativa Mill.) wood by reflectance spectrophotometry and Fourier transform infrared spectroscopy (FTIR) in order to understand the mechanisms that cause changes and to suggest possible solutions to avoid degradation phenomena. The experimental data were statistically treated to evaluate their significance. Concerning the surface protection of wood, starting from the results obtained by testing different commercial products, attention was focused on a novel organic preservative/consolidant product (Linfoil®) that has attracted great interest in the field of conservation of wooden artifacts. Color monitoring showed that wood surface color undergoes an important variation due to photoirradiation, occurring within the first 24 hours and mainly due to L* decrease and b* increase. Though the protective treatment modifies wood color, nevertheless the product tested seems to protect the wood surface by reducing photoyellowing. FTIR analysis indicated that irradiation caused the degradation of lignin and increased the concentration of the chromophore groups on the wood surface. Changes in the chromaticity coordinates can be linked to the degradation of lignin and to increase of the concentration of carbonyl groups. 相似文献
2.
Tiziana Lombardo Marie Wörle Vera Hubert Erwin Hildbrand Christina Hinterleitner Ingo Mayer 《文物保护研究》2020,65(2):65-76
ABSTRACTPreviously, heavy use of biocides for the treatment of objects made of organic materials in museum collections (e.g. ethnographic, historical collections) was very common. Now suitable decontamination methods/technologies are being sought. A decontamination treatment by li-CO2 was optimized that considered the specific requirements of museum objects. The treatment was tested on model materials artificially contaminated with biocide solutions containing dichlorodiphenyltrichloroethane (DDT), pentachlorophenol (PCP), lindane, and permethrin or cypermethrin. High decontamination was achieved for DDT, lindane, PCP, and permethrin on artificially biocide loaded wool and wood model materials. Optimal process parameter settings for li-CO2 decontamination include a single 30?min cycle for woolen materials and three sequential 30?min cycles each for wood. These methods allow a reduction of at least 90% of all biocides for wool and between 70% and 85% for wood. Decontamination of the latter was more effective for less polar biocides as DDT and permethrin. Despite a significant improvement in decontamination for wood using co-solvents such as acetone, ethanol, and methyl tertiary-butyl ether (MTBE), their use is not recommended due to the increased risk of damage to the objects, in particular if a surface coating is present. 相似文献
3.
Nesrin M. N. El Hadidi 《文物保护研究》2017,62(2):83-95
Hardwoods and softwoods were used side by side throughout Egyptian history, and importing softwoods that had an attractive color and texture was common. Over the decades, artifacts based on hardwoods and softwoods underwent deterioration phenomena, sometimes reaching either a level of brittleness or turning into a wood powder that may easily crumble. These levels of decay/degradation are often difficult to handle in terms of conservation treatments. To study or identify the reasons for decay has always been a point of interest for conservation purposes, but to assess decay and choose an appropriate treatment according to the state of preservation for the sake of keeping an artifact intact has become a subject of major importance. It is difficult at times to understand the deterioration process, because hardwoods and softwoods are different in structure, properties, and chemical composition. For this preliminary study, decayed samples from three commonly used softwood types, cypress (Cupressus sp.), cedar (Cedrus sp.), and pine (Pinus sp.), were identified and chosen. Scanning electron microscopy (SEM) of the samples indicated the degree of decay. Decayed and non-aged samples of the same wood type were analyzed using Fourier transform infrared spectroscopy (FTIR), and all the major carbohydrate and lignin bands were recorded. The strong hydrogen bonded (O–H) stretching absorption associated with water linked by hydrogen bonds to the –OH groups of cellulose and hemicelluloses in all decayed samples increased with decay. The brown powdery, fragile samples that had been evidently affected by microbial decay had a higher amount of lignin. The lignin/carbohydrate ratio was calculated and results compared. The increase of either lignin percentage or extractives in some of the samples had caused a darkening of color in both cypress and cedar samples, but the pine sample did not have the same texture and appearance. In cases where the lignin percentage decreased the samples had changed to a slightly lighter color. FTIR results explained the decay phenomena observed in SEM micrographs and helped assess wood decay and also confirmed results that had been previously obtained while applying traditional chemical analysis on wood. 相似文献
4.
《文物保护研究》2013,58(3):162-168
AbstractAs the great majority of photographic prints have a paper support, their conservation has been based on conservation treatments traditionally used by paper conservators. It cannot be assumed, however, that these standard treatments, that are employed on paper without any problem, will give comparable results on photographic prints. The effects of mechanical cleaning, solvent cleaning, wet cleaning, bleaching and deacidification on salted papers, cyanotypes and platinotypes are investigated and discussed. The treatments were separated into those that gave clearly negative results and should be rejected, and those that should be studied in depth before accepting them as suitable. It was shown that the use of some types of bleaching and deacidification agents can be very dangerous in the case of plain paper prints. Cyanotypes proved to be the most sensitive to any treatment method and platinotypes the most resistant. 相似文献
5.
Yanbing Luo 《文物保护研究》2013,58(8):448-455
ABSTRACTTo study the life expectancy and difference in aging resistance properties of different modern repair bamboo papers, hydrothermal/dry-heat ageing experiments on repair bamboo paper samples were conducted. The mechanical strength (tensile strength and folding endurance) of different papers during the ageing process were analyzed. Furthermore, the chemical properties (degree of polymerization and pH) of the samples were tested to search for the immanent cause of paper ageing. The results indicated that the ageing resistance ability and durability of modern repair paper are strongly related to their production process, which corresponds with the initial properties of the paper. Mechanical pulp had a low degradation resistance, which was further exacerbated by the chemical bleaching process. In the long run, traditional handmade papers with solar bleaching processes will have longer-term stability and durability. 相似文献
6.
《文物保护研究》2013,58(3):155-171
AbstractThe presence of iron oxides (lepidocrocite, goethite) in archeological wood may result in a degradation of the wood matrix. Extraction of these iron oxides is largely dependent on their solubility. In this study, balsa wood samples were impregnated with iron oxides to test extraction treatments. Additionally, archeological wood samples were also examined to determine treatment efficiency. Electrophoresis and simple immersion treatments were performed using various chemical solutions: a neutral and a conductive substance (potassium nitrate), an acid (acetic acid), three alkaline chelating agents (tri-ammonium and tri-sodium citrate and sodium oxalate), three acidic and slightly acidic chelating agents (ethylenediaminetetraacetic acid (EDTA), citric acid, and oxalic acid), and a reductant (sodium dithionite). Potassium nitrate did not extract sufficient amounts of iron, irrespective of whether the treatment was conducted by electrophoresis or simple immersion; any observable dissolution was attributed to protonation because of the acidic pH around the anode (as low as 3). Dissolution in acetic acid did not extract iron with either treatment. Strong chelating agents improved extraction, and these compounds gave the best results for simple immersion, particularly EDTA. This chemical is well adapted for use on archeological objects because of its chemical properties (stability constant, speciation based on pH). The addition of sodium dithionite to the solution improved dissolution. Even though electrophoresis improved extraction (in particular for tri-ammonium citrate), none of the tested chelating chemicals were suitable for electrophoresis because of a significant increase in temperature as well as high anode corrosion. The presence of iron sulfide in the archeological wood limited the effectiveness of the tested chemicals. A pre-treatment in sodium persulfate was expanded to include oxidized iron sulfide in oxy/hydroxide iron, which improved the extraction rate. 相似文献
7.
《文物保护研究》2013,58(3):124-136
AbstractIn this study, the following methods of treatment have been studied: bulking with PEG 4000 in water, methanol and t-butanol solvents; bulking with PEG 540 blend in water; bulking with rosin in acetone; freeze-drying from different concentrations of PEG 400 with various methods of pre-freezing; in situ polymerization with glycol methacrylate and with a melamine formaldehyde resin; water displacement with methylene chloride followed by rosin impregnation. They have all been carried out with five groups of waterlogged wood representative of different species and various states of degradation. Freezedrying, PEG 4000 impregnation in t-butanol and PEG 540 blend impregnation in water gave the most satisfactory results, based on appearance and shrinkage. 相似文献
8.
Wood artefacts are subject to damage by biologic infestations due to bacteria, insects, and fungal species. One of the worst feared attacks is due to the xylophagous insects whose larvae feed on wood by boring galleries, at the expense of building timbers and worked woods. These beetles are responsible for daily destruction of the world’s wooden cultural heritage, and their elimination has been always a big problem for conservation of wood. The need to avoid the use of chemical methods in conservation for pest control has led to the development of various non-chemical, non-toxic treatments. Among these, heating with microwaves (MW) seems to be one of the most promising, since it has already shown its high efficacy in destroying pests. Insect-infested wood remediation by MW heating in conservation is based on the larger thermal increment induced in larvae than in wood, due to their different dielectric permittivity in the GHz frequency range. However, the side effects that may occur due to MW heating of wood, such as dehydration, have never been discussed so far. Here we study the possible application of microwave heating as a remediation method for wood samples infested by the larvae of the insect Hylotrupes bajulus. We show that it is possible to set up exposure conditions able to achieve 100% of larvae death and that are sufficiently mild not to induce significant dehydration of the exposed wood from which shrinkage effects may derive. Indeed, under these conditions, MW-induced wood dehydration on cubic and parallelepiped sweetgum samples can be kept under control and to percentages as low as 0.4% (w/w). 相似文献
9.
In retrieving medical free text, users are often interested in answers pertinent to certain scenarios that correspond to common
tasks performed in medical practice, e.g., treatment or diagnosis of a disease. A major challenge in handling such queries is that scenario terms in the query (e.g., treatment) are often too general to match specialized terms in relevant documents (e.g., chemotherapy). In this paper, we propose a knowledge-based query expansion method that exploits the UMLS knowledge source to append the
original query with additional terms that are specifically relevant to the query's scenario(s). We compared the proposed method
with traditional statistical expansion that expands terms which are statistically correlated but not necessarily scenario
specific. Our study on two standard testbeds shows that the knowledge-based method, by providing scenario-specific expansion,
yields notable improvements over the statistical method in terms of average precision-recall. On the OHSUMED testbed, for
example, the improvement is more than 5% averaging over all scenario-specific queries studied and about 10% for queries that
mention certain scenarios, such as treatment of a disease and differential diagnosis of a symptom/disease.
相似文献
| Wesley W. ChuEmail: |
10.
《文物保护研究》2013,58(3):123-132
AbstractVarious methods of bleaching in common use have been studied. Three types of aged paper (rag, chemical and mechanical woodpulp) were washed, deacidified, bleached, deacidified again and artificially aged. The physico-chemical effects of bleaching were measured by the degree of overbleaching, yellowing and loss of mechanical resistance as well as by analysis by electron microprobe and gel permeation chromatography. Seven methods were finally retained and their application is described in detail. 相似文献
11.
《文物保护研究》2013,58(4):308-313
AbstractThe oak timbers of the Swedish warship Vasa are deteriorating. High amounts of oxalic acid have been found along with a low pH and low molecular weight cellulose deep in the wood timbers. The iron-rich surface wood differs from the interior wood in that it displays higher pH and cellulose with higher molecular weight. The objective of this study was to determine why there is a difference in cellulose degradation, pH, and oxalic acid amount between the surface region and the interior of the Vasa timbers. Analysis of cellulose weight average molecular weight by size exclusion chromatography was performed, as well as quantification of oxalic acid and iron by high-performance anion exchange chromatography and atomic emission spectroscopy, respectively. It was found that a decrease in iron content coincides with an increase in oxalic acid concentration and a drop in pH at a certain depth from the wood surface. When iron-rich surface wood samples from the Vasa were mixed with an aqueous solution of oxalic acid, a fast increase of pH over time was observed. Neither interior wood poor in iron nor the fresh oak reference showed the same neutralizing effect during the time of measurement. This indicates that the presence of iron (rust) causes a neutralization of the wood, through the formation of iron(III) oxalato complexes, thus protecting the wood from oxalic acid hydrolysis. This effect was not observed to the same extent for other acids observed in Vasa wood (sulfuric, formic, glycolic, and acetic acids). 相似文献
12.
By far the most common species of woodworms perceived to be the main cause of damage to wood, and in particular to wooden art objects, are Anobium punctatum de Geer and Hylotrupes bajulas of Coleoptera family. In search of non-chemical methods for eradicating these wood pests, microwave (MW) heating can be an effective tool to help control the insects in their different life stages (eggs, larvae, and adult). The effect of 2.45?GHz frequency MW exposure on wooden art objects is described and discussed. MW heating time is reported in connection with lethal temperature of the pest and moisture content of the treated wooden object. The treatment was carried out using Microwood 12, especially conceived for portability, easy operation, and control. Microwood 12 consists of a switch mode high-voltage power supply and an industrial continuous wave magnetron connected to a rectangular-shaped horn antenna. The measure of temperature and control of operation is done via a built-in infrared thermometer. 相似文献
13.
ABSTRACTA decontamination treatment using liquid CO2 (li-CO2) and specifically developed for the requirements of museum objects (Lombardo, T., M. Wörle, V. Hubert, E. Hildbrand, I. Mayer, C. Hinterleitner, U. von Arx. 2020. “Influence of Process Parameters on Chlorinated Biocide Decontamination by li-CO2 on Artificially Contaminated Model Materials.” Studies in Conservation, in press, doi:10.1080/00393630.2019.1641001) was first tested on model materials of wood (with and without coating), silk, and wool with different dyes, paper, and leather in order to evaluate possible material changes. Then, selected museum objects from the collection of the Swiss National Museum were treated to determine the efficiency of biocide decontamination and any resulting chemical and/or structural changes. Results show that dichlorodiphenyltrichloroethane (DDT), pentachlorophenol (PCP), lindane, and chlorpyrifos were successfully removed. Wool, silk, leather, and non-coated wood did not experience any detectable modifications, while moderate to major modifications were observed in wood coated with shellac and polychromy. 相似文献
14.
15.
In paper conservation ethanol is used as an antifungal agent. However, information on the antifungal efficacy of this alcohol is scarce and often inconsistent. In this study, we clarify if ethanol is effective and safe to use in paper conservation in the short as well as in the long term. None of the tested ethanol concentrations (5–100%) promoted conidia germination, but rather delayed or entirely inhibited it, depending on alcohol concentration and contact time. In a simulation of an interventive treatment of samples colonized by fungi, all the tested ethanolic solutions (30, 70, and 100%) revealed antifungal activity. The best results were obtained with 70% ethanol, showing fungicidal properties on four of the five-tested fungal species (Aspergillus niger, Cladosporium cladosporioides, Penicillium chrysogenum, and Penicillium corylophilum). No deleterious effects of 70% ethanol on the tested paper were observed either in the short or in the long term. 相似文献
16.
AbstractPolyethylene glycols (PEG) can be detected in wood by their in situ formation of coloured complex compounds. Solutions of potassium bismuth iodide/barium chloride and of bromine/potassium iodide are suitable for sprayingdirectly onto wood, and may even be used on dark-coloured wood by mixing chalk powder into the reagent. By adopting a print-off technique onto damp filter paper, the distribution of PEG in wood can be demonstrated even more exactly, even from very small samples. Print-offs are developed into differentiated coloured pictures withsolutions of potassium bismuth iodide/barium chloride, iodine/potassium iodide or ammonium cobalt (II) thiocyanate. 相似文献
17.
《Communication methods and measures》2013,7(4):331-340
In recent years, reporting estimates of effect size have become more important in social and behavioral science research. Four full volumes (2003–2006) of four influential communication journals were examined. The findings show that the rate of reporting effect size was very high for some types of statistical analyses (e.g., correlation, regression), and considerably lower for others (e.g., t-test, χ 2 test). The results provide a picture about the current state of affairs in terms of effect size reporting in communication research. 相似文献
18.
《文物保护研究》2013,58(3):143-154
AbstractSince 1980, much research in the field of treatment and conservation of archaeological wood has been carried out at the Conservation Department, Faculty of Archaeology, Cairo University. Materials and methods used in conservation have been changing gradually over the years worldwide. It was necessary to study critically previous masters and doctoral dissertations on Egyptian archaeological and historic wood, all written in Arabic. This review of them includes a brief history of the Conservation Department at Cairo University and five main focal points of past research: types of wood used throughout Egyptian history, assessment of wood decay, wood properties and composition, treatment and conservation of decorated wood, and the evaluation of chemicals and polymers used in the treatment of archaeological wood and composite objects containing wood. 相似文献
19.
《文物保护研究》2013,58(3):256-268
AbstractThis work investigates the use of micro-computed tomography (micro-CT) for identification of New Zealand plant leaf material from artefacts. Micro-CT was explored as a result of difficulties in preparing transverse sections from aged plant material artefacts to compare with reference slides for microscopic identification of plant species. Plant names in te reo Māori (Māori language) are followed by the English name and botanic name, and are subsequently referred to by Māori names. The three plants investigated (harakeke, New Zealand flax, Phormium tenax, J. R. Forst & G. Forst; tī kōuka, cabbage tree, Cordyline australis, (Forst.f.) Endl,; kiekie, Frecinetia banksii A.Cunn.) were/are commonly used by Māori for the manufacture of objects often found in cultural institutions. Contemporary and historical specimens (from artefacts) of plant leaf material were investigated. Contemporary specimens were viewed using micro-CT and showed identifiable features compared with micrographs of transverse sections from reference material. Diagnostic features of each plant species were then named and measured, providing the basis for development of an identification key using both visual and objective criteria. Positive identification of historical specimens using this key varied across plant species and according to level of ageing and processing. Despite this, micro-CT had several advantages over traditional transverse sections: samples were not prepared for, or altered by, analysis, and numerous cross sections across the entire sample could be easily viewed to locate identifiable characteristics. Although measurable criteria supplied apply only to the three named New Zealand plant species, this paper provides methods that could be applied to the identification of other aged plant leaf material. Knowledge of plant anatomy at the level of major cell and tissue types (e.g. mesophyll, sclerenchyma, vascular tissue, and epidermis) is sufficient for the level of analysis carried out in this study. 相似文献