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1.
Wood artefacts are subject to damage by biologic infestations due to bacteria, insects, and fungal species. One of the worst feared attacks is due to the xylophagous insects whose larvae feed on wood by boring galleries, at the expense of building timbers and worked woods. These beetles are responsible for daily destruction of the world’s wooden cultural heritage, and their elimination has been always a big problem for conservation of wood. The need to avoid the use of chemical methods in conservation for pest control has led to the development of various non-chemical, non-toxic treatments. Among these, heating with microwaves (MW) seems to be one of the most promising, since it has already shown its high efficacy in destroying pests. Insect-infested wood remediation by MW heating in conservation is based on the larger thermal increment induced in larvae than in wood, due to their different dielectric permittivity in the GHz frequency range. However, the side effects that may occur due to MW heating of wood, such as dehydration, have never been discussed so far. Here we study the possible application of microwave heating as a remediation method for wood samples infested by the larvae of the insect Hylotrupes bajulus. We show that it is possible to set up exposure conditions able to achieve 100% of larvae death and that are sufficiently mild not to induce significant dehydration of the exposed wood from which shrinkage effects may derive. Indeed, under these conditions, MW-induced wood dehydration on cubic and parallelepiped sweetgum samples can be kept under control and to percentages as low as 0.4% (w/w). 相似文献
2.
《文物保护研究》2013,58(4):307-315
AbstractThe application of triangulation laser displacement sensors to the continuous in-situ monitoring of the response of wooden cultural objects to variations in temperature and relative humidity in their environment is reported. The sensors are robust, fast and precise, provide non-contact measurements, and are capable of operating in the field. They have been applied to monitor the response of the altarpiece in the church of Santa Maria Maddalena in Rocca Pietore, Italy, to fluctuations in temperature and relative humidity caused by the use of the heating system. Complex short-, medium- and long-term responses of a variety of carved wooden elements have been recorded. 相似文献
3.
《文物保护研究》2013,58(2):65-79
AbstractEnvironmental standards for cultural heritage collections have been much debated in recent years. The interest in the issue has been driven by the growing movement towards green museums, that is, managing indoor museum environments in a responsible and efficient manner, especially in terms of reducing energy consumption and carbon emissions but at the same time maintaining high standards of collection care. Painted wood is among the category of heritage objects most vulnerable to relative humidity and temperature fluctuations. Therefore, scientific understanding of how changes in environmental conditions ultimately affect painted wood is crucial to the development of rational guidelines for the control of climate in museums and historic buildings. This review provides a systematic progression through two fundamental approaches to establish the allowable ranges of climatic variations – an analysis of the mechanical response of painted wood as a complex, multilayer system to climate variations, and an analysis of the historic climate to which the objects have acclimatized. The climate specifications and standards based on both these approaches are reviewed. 相似文献
4.
《文物保护研究》2013,58(2):118-122
AbstractThis paper deals with the materials used in conservation treatments in the first half of the twentieth century for the preservation and consolidation of wooden art objects from the Saxony region in Germany. The use of such materials must be seen as early attempts to find a conservation treatment for wood. The documentation of conservation treatments provides a reference to the application of oils and oil–resin mixtures. The results from the chemical analysis of samples of historic preservatives from the beginning to the middle of the twentieth century (so-called 'Puckelin') carried out by gas chromatography–mass spectrometry (GC-MS) and Fourier transform infrared (FTIR) analysis confirm the use of tung oil as a drying oil, whereas the use of linseed oil cannot be excluded. Colophony and, probably, amber varnish were used as resinous constituents. There are indications that a conservation material dating from the second half of the twentieth century most likely contained rapeseed oil. 相似文献
5.
Kate Fulcher 《文物保护研究》2017,62(4):210-222
The conservation of wooden objects is complicated by their response to changes in their environment. In particular, filling voids in wooden objects can be difficult when their dimensions might be expected to alter over time. A short survey of conservators showed that a wide variety of materials have been, and are being used for this purpose. Following conservation work undertaken on a wooden coffin, the author wished to investigate the properties of cellulosic materials and their suitability in the conservation of wooden objects. This paper shares the results of experiments that were conducted to determine the way in which hydroxypropyl cellulose (HPC) and paper pulp fills respond in various conditions, as compared to other fill materials used by conservators. The compatibility of the HPC and paper pulp fills with wood is satisfactory enough to be able to recommend their use in the conservation of wooden artefacts, but ideally further experiments would be carried out, and on a wider variety of fill materials. 相似文献
6.
Light-induced color changes and chemical modification of treated and untreated chestnut wood surface
AbstractThe aim of this work is to study the surface modifications of chestnut (Castanea sativa Mill.) wood by reflectance spectrophotometry and Fourier transform infrared spectroscopy (FTIR) in order to understand the mechanisms that cause changes and to suggest possible solutions to avoid degradation phenomena. The experimental data were statistically treated to evaluate their significance. Concerning the surface protection of wood, starting from the results obtained by testing different commercial products, attention was focused on a novel organic preservative/consolidant product (Linfoil®) that has attracted great interest in the field of conservation of wooden artifacts. Color monitoring showed that wood surface color undergoes an important variation due to photoirradiation, occurring within the first 24 hours and mainly due to L* decrease and b* increase. Though the protective treatment modifies wood color, nevertheless the product tested seems to protect the wood surface by reducing photoyellowing. FTIR analysis indicated that irradiation caused the degradation of lignin and increased the concentration of the chromophore groups on the wood surface. Changes in the chromaticity coordinates can be linked to the degradation of lignin and to increase of the concentration of carbonyl groups. 相似文献
7.
《文物保护研究》2013,58(3):110-157
AbstractConsolidation of decayed wooden artifacts can be achieved by impregnation with epoxy prepolymer dissolved in a mixture of toluene and glycidyl ether and subsequent polymerization in situ. The principles of selecting the successful method of application are discussed, and the details of the procedure given. Impregnation with the described solution causes insignificant expansion of the wood in contrast to the action of polyvinyl acetate in alcohol solution. 相似文献
8.
AbstractJapanese sculptures are made of wood, dry lacquer, clay, gilt bronze and stone. Buddhistic statues, made of wood, are the most abundant. The painting techniques of the wooden sculptures, including ground coating, pigments, and application of Japanese lacquer, are described, and typical examples of Buddhistic statues are given. Specific case studies on a clay statue and a wooden sculpture are made. 相似文献
9.
ABSTRACTConservation of wooden objects exposed outdoors is extremely difficult and complex due to their constant exposure to fluctuating weather conditions and biological degradation. Filling the gaps in such objects requires the use of specific materials that in particular can adapt to changes in wood dimensions in response to humidity variations. Various materials have been used so far for filling voids in wooden artefacts but none of them was entirely suitable. Therefore, the authors have attempted to provide the basic characteristics of the selected commonly used filling materials based on pine wood powder or glass microballoons as fillers and Paraloid® B-72, Klucel® G, or glutin glue as binders, as the first step in research aiming at developing new and more appropriate gap-fillers. Special attention was paid to the dimensional stability of filling materials upon drying and exposure to water vapour and liquid water. The overall results indicate that among the examined fills those consisting of Paraloid® B-72 and glass microballoons revealed best properties as they were relatively dimensionally stable upon drying and exposure to moisture – despite high absorption of water – and were quite easy to finish. Generally, better properties were observed for filling materials containing higher concentrations of adhesives and these materials will be modified in the next step of the research. Since the main drawbacks of the examined gap-fillers were low water resistance, poor dimensional stability upon drying or exposure to water vapour or liquid water, and fragility or friability, future research into their modification will head towards improvement of the above-mentioned properties. 相似文献
10.
《文物保护研究》2013,58(1):135-139
AbstractBibliographical research and scientific analysis of samples obtained from five polychrome wooden sculptures of the colonial tradition in Guatemala were used to study the techniques and the materials used. The methodology involved qualitative analysis of the samples and microscopic examination of cross-sections. Scanning electron microscopy (SEM) was used to identify pigments and to ascertain the composition of the gilding. It was hypothesized that the deterioration of the sculptures, particularly the separation of the ground layers from the wooden support, was due to the action of secondary products of Cedrela odorata L. The loss of adhesion of the animal glue used in the preparation may be partly related to the precipitation of the protein of the gelatin due to the action of the tannins present in the wood. 相似文献
11.
This article describes the investigation of white efflorescence on eight wooden African objects from Malawi and Zambia and the treatment of the objects to remove the deposits. The source of the efflorescence on these objects was determined to be the heartwood from which they were carved. Using gas chromatography-mass spectrometry and Fourier transform infrared spectrometry, the crystalline efflorescence was found to consist of homopterocarpin and pterocarpin, two isoflavonoid compounds found in woods and shrubs belonging to the genus Pterocarpus, and African Baphida nitida. The crystal growth appeared to be heaviest on areas of the objects that were more deeply carved as well as on those objects without a surface finish. The storage conditions of the collection were studied and found to have likely accelerated the rate and extent of the natural movement of the pterocarpan compounds from the interior of the heartwood to the outer surfaces. 相似文献
12.
《文物保护研究》2013,58(2):56-66
AbstractThere is evidence in the literature that in India wood was used for making sculptures from very early times. Owing to the destructive climate, however, only wooden objects dating from the 7th century are available today, while polychromed wooden sculptures of the period before the 16th century are unobtainable. Sculptures were produced either by carving from one solid block or by building it up from small pieces. The main types of decorating were painting, inlay work or lac work. Painting was done sometimes without, but mostly with surface preparation. For this a thin layer of a ground was used. Sometimes a layer of cloth and then paper was used before applying the gesso. Pigments in common use were malachite, terre-verte, red ochre, red lead, lac dye, yellow ochre, chrome yellow, ultramarine, kaolin, and chalk. A gold effect was often produced by applying shellac varnish over shining silvery tin paint or foil. Lac work was produced by painting with lac solution or by turnery. 相似文献
13.
《文物保护研究》2013,58(1):6-10
AbstractA sixteenth-century Spanish wooden ceiling was installed in the Morning Room of Hearst Castle in the early 1920s. Since that time, the adhesion between the ground/paint layer and its wooden support has weakened considerably. As a first step in designing an effective conservation program, it was necessary to assess the role of the environment in this deterioration process. Air movement patterns, humidity and temperature parameters, air pollutants, and the impact of approximately one million visitors per year on the microclimate were studied over a one-year period. Correlations between the various components of the study were mapped, including CO2 concentrations vis-à-vis the number of visitors, and humidity and temperature changes in relation to tourists, air circulation patterns and variations in the external climate. As a result of this study, temporary measures were taken to improve the conditions of the immediate environment and proposals were made for more permanent solutions. 相似文献
14.
Michal Łukomski Vincent Beltran Foekje Boersma James Druzik Ashley Freeman Marcin Strojecki 《文物保护研究》2018,63(5):181-186
ABSTRACTThis experimental program, implemented by the Managing Collection Environment Initiative at the Getty Conservation Institute, has provided data about the response of historic objects to changes in relative humidity (RH). Alongside other less sensitive documentation techniques (visual observation, physical measurements, photography, and 3D scanning), acoustic emission (AE) was monitored for six historic, museum-like wooden objects exposed to gradually increasing RH variations. Quantitative calibration of AE sensors and an anti-correlation measuring scheme to reduce environmental noise allowed the AE system to effectively trace micro-damage development caused by environmentally induced stress. Using an epidemiological approach, with respect to sample selection and experimental protocol, the obtained results can be used to explore the acceptable range of climate fluctuations for museum collections. The study’s well-controlled environmental protocol also allowed for the examination of the concept of ‘proofed fluctuation’ by the analysis of object response to reoccurring conditions. 相似文献
15.
《文物保护研究》2013,58(5):333-339
AbstractWhen wooden supports of panel paintings have been severely altered or damaged and the original cross beams are missing, new cross beams or other types of auxiliary supports are connected to the panel's back-face in order to achieve desired effects including panel strengthening and control of deformations. Some conservation laboratories use small wooden blocks, each glued on the back face of the panel and holding freely the head of a screw connected (often by means of springs) to the auxiliary support; such blocks being called in Italian ‘piedini’ or ‘bottoni’, the English term ‘buttons’ is proposed here. This paper reports research aiming to characterize the mechanical behavior of three types of ‘buttons’ having different geometries and made of various wood types (oak, walnut, lime, beech, and a medium density fiberboard). Short-term mechanical tests (～1 minute duration) were performed with a universal testing machine by axially pulling out the 4 mm diameter steel screw from the button, glued onto a dummy board. Load and deformation were recorded, and the load–deformation curves were analyzed. The results show that the deformability and the load-carrying capacity of the buttons were influenced primarily by the manufacturing geometry and secondarily by the wood density. 相似文献
16.
Natural polymers as alternative consolidants for the preservation of waterlogged archaeological wood
In recent years, there has been increased interest in examining alternative polymers for the conservation of archaeological artefacts, particularly waterlogged timbers, providing better, renewable, greener alternatives to poly(ethylene glycol) (PEG). The degradation of PEG consolidants in the timbers of the sixteenth century warship Mary Rose has been examined and the rheological and thermal properties of PEG have been compared with its monomethyl and dimethyl ethers and several polysaccharide consolidants (chitosan, guar, and 2-hydroxyethyl cellulose) in order to evaluate their potential as alternative consolidants for the conservation of waterlogged wooden artefacts. Additionally, the effect of the polymers on the archaeological wood was characterised by thermogravimetric analysis and solid-state nuclear magnetic resonance spectroscopy. The results suggest that the future of conservation technologies lies with polysaccharide consolidant materials, which show enhanced compatibility with wooden artefacts with no detectable side effects while also being cheap, with extremely low toxicity, renewable, and sustainably resourced. 相似文献
17.
《文物保护研究》2013,58(1):165-167
AbstractInsect infestation is a serious problem in museum collections in Spain and Latin America. This paper investigates the efficacy of modified atmospheres as an anoxant for museum pests, using wooden objects including polychrome sculptures infested by Cerambycidae and Anobiidae species. Insects of long life cycle have been found to be very resistant to carbon dioxide atmospheres. However, inert gases such as argon and nitrogen used in plastic barrier bags effectively eliminated insects in all stages of development. No chemical alteration was observed in the treated materials, including polychromy. These treatments are in progress in a project for biodeterioration control in countries with both tropical or subtropical and Mediterranean climates. 相似文献
18.
ABSTRACTA decontamination treatment using liquid CO2 (li-CO2) and specifically developed for the requirements of museum objects (Lombardo, T., M. Wörle, V. Hubert, E. Hildbrand, I. Mayer, C. Hinterleitner, U. von Arx. 2020. “Influence of Process Parameters on Chlorinated Biocide Decontamination by li-CO2 on Artificially Contaminated Model Materials.” Studies in Conservation, in press, doi:10.1080/00393630.2019.1641001) was first tested on model materials of wood (with and without coating), silk, and wool with different dyes, paper, and leather in order to evaluate possible material changes. Then, selected museum objects from the collection of the Swiss National Museum were treated to determine the efficiency of biocide decontamination and any resulting chemical and/or structural changes. Results show that dichlorodiphenyltrichloroethane (DDT), pentachlorophenol (PCP), lindane, and chlorpyrifos were successfully removed. Wool, silk, leather, and non-coated wood did not experience any detectable modifications, while moderate to major modifications were observed in wood coated with shellac and polychromy. 相似文献
19.
Martin Nordvig Mortensen Gilles Chaumat Francesca Gambineri Hartmut Kutzke Jeannette Jacqueline Łucejko Caitlin M. A. McQueen 《文物保护研究》2013,58(2):115-123
ABSTRACTSamples of conserved archaeological wood of different ages, origins, and conservation histories were aged in a climate chamber for seven months, while the humidity alternated between 30% RH for 12 hours and 80% RH for 12 hours at a constant temperature of 30°C. Photographs were taken once every hour, which enabled the creation of a time-lapse movie. Some samples degraded visibly, whereas others were unaffected. Most of the samples were robust and would be able to survive well even in a very poor museum climate. Among the sensitive samples, three types of degradation were identified, namely disintegration, pyrite oxidation, and efflorescence of white crystals. Disintegration was ascribed to dimensional changes caused by the RH alternations in very fragile wood. The white efflorescence was interpreted as the recrystallization of an alum-associated substance, possibly mercallite (KHSO4). The pyrite oxidation was observed as the efflorescence of a thick yellow, grey, and green powder. Characterization of selected samples was performed using X-ray fluorescence spectrometry, X-ray diffraction spectrometry, scanning electron microscopy with energy dispersive X-ray spectroscopy, inductively coupled plasma – optical emission spectroscopy, Fourier transform infrared spectroscopy, ionic conductivity – liquid chromatography, and pyrolysis-gas chromatography-mass spectrometry with in situ silylation using hexamethyldisilazane. 相似文献
20.
《文物保护研究》2013,58(4):308-313
AbstractThe oak timbers of the Swedish warship Vasa are deteriorating. High amounts of oxalic acid have been found along with a low pH and low molecular weight cellulose deep in the wood timbers. The iron-rich surface wood differs from the interior wood in that it displays higher pH and cellulose with higher molecular weight. The objective of this study was to determine why there is a difference in cellulose degradation, pH, and oxalic acid amount between the surface region and the interior of the Vasa timbers. Analysis of cellulose weight average molecular weight by size exclusion chromatography was performed, as well as quantification of oxalic acid and iron by high-performance anion exchange chromatography and atomic emission spectroscopy, respectively. It was found that a decrease in iron content coincides with an increase in oxalic acid concentration and a drop in pH at a certain depth from the wood surface. When iron-rich surface wood samples from the Vasa were mixed with an aqueous solution of oxalic acid, a fast increase of pH over time was observed. Neither interior wood poor in iron nor the fresh oak reference showed the same neutralizing effect during the time of measurement. This indicates that the presence of iron (rust) causes a neutralization of the wood, through the formation of iron(III) oxalato complexes, thus protecting the wood from oxalic acid hydrolysis. This effect was not observed to the same extent for other acids observed in Vasa wood (sulfuric, formic, glycolic, and acetic acids). 相似文献