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1 Introduction Organiclight emittingdiodes(OLEDs)haveattract edconsiderableattentionduetoitsgreatpotentialinefficiency ,low voltage ,large area ,lightweight ,andfull colorflat paneldisplays[1,2 ] .Forfull colordis plays ,itisnecessarytohaveefficientred ,green ,andblueemitterswithappropriatechromaticity .Bycom parisonwiththehighperformanceofblueandgreenOLEDs ,theperformanceandpurechromaticityofredOLEDsarestillrelativelypoor .UsuallyredOLEDsareimprovedbydopingreddyesintohostmaterialswit…  相似文献   
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A kind of pyrazoline derivative 1,3-bis(phenyl)-5-(2-phenanthrene)-2-pyrazoline(TPp) was synthesized in order to obtain stable film and applied to organic electroluminecsent diode as hole transporting material. Two devices with structures as indium-tin-oxide(ITO) TPP (50 nm)/tris-(8-hydroxyquinoline) aluminum(Alq3) (50 nm)/Al (150 nm) and ITO /TPP (50 nm)/lithium tera-(8-hydroxy-uinolinato)boron(LiBq4 (50 nm)/Alq3 (5 nm)/Al (150 nm) were fabricated, they showed good electroluminescent(EL) performance and TPP was proved to be a good hole transporting material.  相似文献   
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Two types of molecular and polymer devices employing (2-(4′-biphenyl)-5-(4““““““““-tert-butylphenyl)-1,3,4-oxadiazole) (PBD)and poly(N-vinylcarbazole) (PVK) as electron transport and hole transport materials, respectively, have been fabricated. The structures of these two devices are ITO/PVK( 70 nm)/PBD(60 nm)/A1 and ITO/PVK: PBD (1:1 by mass, 70 nm)/A1. The formation of exciplex is evident by comparing the electroluminescence (EL) of a bi-layer device and the photoluminescence (PL) of a PVK and PBD mixed film.The maximum emission energy of exciplex evaluated is consistent with the peak emission of EL. Blue emissions from both devices are obtained. The type of exicplex is interpreted based on the energy level diagram of the bi-layer device.  相似文献   
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1Introduction Sincethefirstreportofefficientorganiclightemit tingdevices(OLED)byTang[1],OLEDshavebeen emergingastheleadingcandidateforthenextgenera tionplat paneldisplaysduetotheiradvantagessuchas fastresponsetime,largeviewingangle,highbright ness,lowoperatingvoltageandverythinthickness.Generally,theemissioncolorsoflayeredOLEDscan beabtainedbyselectingfluorescentmaterialswithdif ferentenergylevelsgapordopingtheorganicfilms withhighlyefficientfluorescentdopants.Sometimes,foracertaincombina…  相似文献   
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In order to compare two kinds of blue electroluminescent materials,we have investigated two kinds of blue OLEDs with the similar structure ITO/CuPc/NPB/JBEM:perylene/Alq/Mg:Ag[device(J)] and ITO/CuPc/NPB/DPVBi:perylene/Alq/Mg:Ag[device(D)].The difference of luminance and efficiency was not obvious for the two devices,However,there was remarkable difference for their lifetime.The device(J) achieved longer half lifetime of 1035h at initial luminance of 100 cd/m^2,and that of device(D) was only255h,According to their energy level diagrams,the differentce of their stability may originate from different host materials in the two devices.It may be attributed to the better thermal stability of JBEM molecues than that of DPVBi.It is shown that JBEM may be a promising blue organic electroluminescent material with great stability.  相似文献   
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Three types of blue-violet light-emitting devices based on an exciton-confined structure have been prepared, in which different materials were used as emitting layers and hole-transporting layers. They had structures of ITO/CuPc/NPB/CPB/TPBi/Alq3/LiF/Al(DNC), ITO/CuPc/JO3/CBP/TPBi/Alq3/LiF/Al(DJC ) and ITO/CuPc/JO3/FNPD/TPBi/Alq3/LiF/Al(DJF). Here copper phthalocyanine (CuPc) acted as hole-injecting layer( HIL), N, N-bis-(1-naphthyl)-N, N-diphenyl-1. lbiphenyl-4-4-diamine(NPB) and J03 bole-transporting layers ( HTLs), 4,4‘-dicarbazolyl-1,1‘ -biphenyl (CBP) and FNPD as emitting layers( EMLs), N, arylbenzimidazoles (TPBi) as holeblocking layer ( HBL ), and tris(8-quinolinolato ) aluminium complex ( Alq3 ) as electron- transporting layer ( ETL). TPBi applied here is a good confinement to both charges and excitons, which make the devices emit blue-violet light originating from the emitter, CBP and FNPD. Their characteristics have also been investigated. The result shows that the device DNC based on NPB/CBP has the best performance among the three devices. The excellence of DNC is attributed to the better hole-transporting ability of NPB as compared with J03, and the better emitting ability of CBP as compared with FNPD, although the best matching of energy levels is found in the hole-transporting layer and emitting layer of the device DJP.  相似文献   
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A new blue electroluminescent material,distyrylarylene(DSA)derivative,4,4‘-bis[2,2-(1-naphthyl,phenyl)vinyl]-1,1-biphenyl(NPVBi)is designed and synthesized.The DSA derivative shows better thermal stability because of its high glass transition temperature.A blue organic light emitting diode(OLED0with the structure ITO/TPD/NPVBi/Alq/LiF/Al is studied.The electroluminescent(EL0spectrum of the OLED exhibits that light emission originates from NPVBi with a peak at 460nm,its Commission Internationale de l‘Eclairage(CIE)color coordinates are x=0.16,y=0.15,and showing independence of CIE color coordinates on current density.The new DSA derivative is expectable as a new candidate for blue light emitter in OLEDs.  相似文献   
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