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Yun-kui Liu Da-jie Mao Shao-jie Lou Jian-qiang Qian Zhen-yuan Xu 《Journal of Zhejiang University. Science. B》2009,10(6):472-478
In this paper, we presented a novel method for the facile and efficient one-pot synthesis of 2-arylbenzoxazoles, which oxygen atmosphere with anhydrous tetrahydrofuran (THF) as solvent or in solvent-free condition. The results show that this method could bring excellent yields as high as 96%. THF was proven to be the best choice among several solvents screened and the reaction was tolerated with a variety of aromatic aldehydes possessing electron-donating or withdrawing groups. The advantages of the present method lie in catalytic process using economic and environmentally benign dioxygen as oxidant. 相似文献
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WANG Xiu-li TU Jiang-ping CHEN Chang-pin ZHANG Xiao-bin ZHAO Xin-bing 《Journal of Zhejiang University. Science. B》2005,(3)
Mg2Ni0.8Cr0.2-x wt.% CoO/Al2O3 (x=0.5, 1, 2 and 3) composites were prepared by mechanically milling sintered Mg2Ni0.8Cr0.2 alloy and CoO/Al2O3 compound for 45 h. The addition of CoO/Al2O3 compound resulted in the good kinetics properties of hydriding/dehydriding reaction of the composites. The composite with 1.0 wt.% CoO/Al2O3 catalyst could reach the maximum hydrogen absorption capacity (2.9 wt.%) within 5 min at 393 K under H2 pressure of 4 MPa, and can desorb rapidly at 493 K. The decomposition and synthesis of hydrogen molecule on Mg2Ni0.8Cr0.2 alloy surface was promoted by addition of CoO/Al2O3 catalyst. In addition, the formation of metallic Ni particles, strain and defects during the ball milling process also resulted in the improved hydrogenation performance of Mg2Ni-based alloys. 相似文献
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INTRODUCTION With the development of industry, more and more pollutants are discharged into environment, among them, phenolic wastes are typical contami-nants considered to be hazardous and top priority toxic pollutants listed by the USEPA. They are toxic even at low concentration. Due to their biorefractory, bioaccumulation and carcinogenic potential, the treatment of these contaminants is very important in environmental protection. Various technologies and processes have been tried … 相似文献
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In this paper, through the study of thermal conductivity of hydrogen- argon mixture at different temperatures for thermal insulation pipes in petroleum industry, a good method for determining the therm... 相似文献
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This study investigated the alleviating effects of hydrogen sulfide (H2S), derived from sodium hydrosulfide (NaHS), on inflammation induced by dextran sulfate sodium (DSS) in both in vivo and in vitro models. We found that NaHS injection markedly decreased rectal bleeding, diarrhea, and histological injury in DSS-challenged mice. NaHS (20 µmol/L) reversed DSS-induced inhibition in cell viability in Caco-2 cells and alleviated pro-inflammation cytokine expression in vivo and in vitro, indicating an anti-inflammatory function for H2S. It was also found that H2S may regulate cytokine expression by inhibiting the nuclear factor-κB (NF-κB) signaling pathway. In conclusion, our results demonstrated that H2S alleviated DSS-induced inflammation in vivo and in vitro and that the signal mechanism might be associated with the NF-κB signaling pathway. 相似文献